氢氧化过氧化氢的光催化制备新方法。通过Mannich反应合成苯并恶嗪并经聚合、球磨制得微米级催化剂Micro-PBZ,在可见光下O2饱和水溶液中实现86.39 μmol·h?1的高产率,11次循环稳定性良好。DFT计算表明其共轭结构、 tertiary胺基团及π-π堆积促进电荷分离和O2活化,抗 ...
The Nature Index 2025 Research Leaders — previously known as Annual Tables — reveal the leading institutions and countries/territories in the natural and health sciences, according to their output in ...
The Nature Index 2025 Research Leaders — previously known as Annual Tables — reveal the leading institutions and countries/territories in the natural and health sciences, according to their output in ...
Smart citations by scite.ai include citation statements extracted from the full text of the citing article. The number of the statements may be higher than the number of citations provided by ACS ...
Normal aerobic metabolism (via processes such as photosynthetic and respiratory electron transport chains) in plants yields varied reactive oxygen species (ROS) such as singlet oxygen (1O2), ...
电化学双电子氧还原反应(2e- ORR)生成过氧化氢(H2O2)是一种很有前途的替代高能蒽醌工艺的方法,然而,在设计符合应用标准的2e- ORR催化剂方面仍然存在挑战。 基于此,苏州大学康振辉教授,邵名望教授,邵琪副研究员,杨昊,廖凡(共同通讯作者)等人 ...
环氧丙烷(PO)是生产聚氨酯、聚酯、丙二醇等工业化学品的重要中间体。目前,生产PO的主要方法是氯醇法和共氧化法,这两种方法的加工过程都很复杂,而且容易产生多种有害副产品。以钛硅分子筛(TS-1)为催化剂,H2O2为氧化剂,甲醇(CH3OH)为溶剂的H2O2氧化生产PO ...